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4-溴苯甲醯氯

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4-溴苯甲醯氯
別名 對溴苯甲醯氯
識別
CAS號 586-75-4  checkY
PubChem 68515
性質
化學式 C7H4BrClO
摩爾質量 219.46 g·mol−1
熔點 42 °C(315 K)
沸點 246 °C(519 K)
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

4-溴苯甲醯氯是一種有機化合物,化學式為C7H4BrClO,它是苯甲醯氯苯環對位的氫被溴取代的化合物。它可由4-溴苯甲酸草醯氯二甲基甲醯胺的催化下於二氯甲烷中反應得到[1],醯氯化試劑也可使用氯化亞碸[2]。它和苯胺三乙胺的存在下於四氫呋喃中反應,可以得到N-苯基-4-溴苯甲醯胺。[3]

參考文獻

[編輯]
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  2. ^ Hugo Gallardo, Rodrigo Cristiano, André Vieira, Ricardo Neves Filho, Rajendra Srivastava. Sonogashira Coupling Applied in the Synthesis of 1,2,4-Oxadiazole-Based Nonsymmetrical Liquid Crystals. Synthesis. 2008-02, 2008 (4): 605–609 [2021-09-20]. ISSN 0039-7881. doi:10.1055/s-2008-1032156. (原始內容存檔於2018-06-03) (英語). 
  3. ^ Clarice A. D. Caiuby, Matheus P. de Jesus, Antonio C. B. Burtoloso. α-Imino Iridium Carbenes from Imidoyl Sulfoxonium Ylides: Application in the One-Step Synthesis of Indoles. The Journal of Organic Chemistry. 2020-06-05, 85 (11): 7433–7445 [2021-09-20]. ISSN 0022-3263. doi:10.1021/acs.joc.0c00833. (原始內容存檔於2021-11-07) (英語).