甲基二苯基膦

甲基二苯基膦
别名	Diphenylmethylphosphine; Methyldiphenylphosphane;
识别
CAS号	1486-28-8
PubChem	73879
SMILES	CP(C1=CC=CC=C1)C2=CC=CC=C2;
InChI	1S/C13H13P/c1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3;
InChIKey	UJNZOIKQAUQOCN-UHFFFAOYSA-N
性质
化学式	C13H13P
摩尔质量	200.22 g·mol−1
密度	1.0779
熔点	117—118 °C（390—391 K）
沸点	284 °C（557 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

甲基二苯基膦是一种有机化合物，化学式为C₁₃H₁₃P。它可由甲基溴化镁和二苯基氯化膦在乙醚中反应制得。^[2]甲基二苯基氧化膦被苯硅烷还原，也能得到甲基二苯基膦。^[3]它和硫或硒反应，可以得到相应的硫化膦或硒化膦。^[4]它和氯化镍反应，得到配合物二氯化二(甲基二苯基膦)合镍。^[5]

参考文献

^ Min Shi, Wen Zhang. Organocatalysts of tertiary-phosphines and amines catalyzed reactions of α-keto esters with cyclopent-2-enone. Tetrahedron. 2005-12, 61 (50): 11887–11894 [2021-09-30]. doi:10.1016/j.tet.2005.09.067. （原始内容存档于2020-02-16）（英语）.
^ László T. Mika, László Orha, Norbert Farkas, István T. Horváth. Efficient Synthesis of Water-Soluble Alkyl-bis( m -sulfonated-phenyl)- and Dialkyl-( m -sulfonated-phenyl)-phosphines and Their Evaluation in Rhodium-Catalyzed Hydrogenation of Maleic Acid in Water. Organometallics. 2009-03-09, 28 (5): 1593–1596 [2021-09-30]. ISSN 0276-7333. doi:10.1021/om800570r （英语）.
^ Tamara Kovács, Anita Urbanics, Flóra Csatlós, György Keglevich. A study on the deoxygenation of trialkyl-, dialkyl-phenyl- and alkyl-diphenyl phosphine oxides by hydrosilanes. Heteroatom Chemistry. 2017-07, 28 (4): e21376 [2021-09-30]. doi:10.1002/hc.21376 （英语）.
^ Aagaard, Olav M.; Janssen, Rene A. J.; Buck, Henk M. An ESR study on electron-capture phosphorus-centered radicals in solid matrixes of alkyl/phenylphosphine sulfides and selenides. Recueil des Travaux Chimiques des Pays-Bas, 1989. 108 (7-8): 262-267. ISSN 0165-0513.
^ Eric A. Standley, Stacey J. Smith, Peter Müller, Timothy F. Jamison. A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes. Organometallics. 2014-04-28, 33 (8): 2012–2018 [2021-09-30]. ISSN 0276-7333. PMC 4006606 . PMID 24803717. doi:10.1021/om500156q （英语）.

[1] Min Shi, Wen Zhang. Organocatalysts of tertiary-phosphines and amines catalyzed reactions of α-keto esters with cyclopent-2-enone. Tetrahedron. 2005-12, 61 (50): 11887–11894 [2021-09-30]. doi:10.1016/j.tet.2005.09.067. （原始内容存档于2020-02-16）（英语）.

[2] László T. Mika, László Orha, Norbert Farkas, István T. Horváth. Efficient Synthesis of Water-Soluble Alkyl-bis( m -sulfonated-phenyl)- and Dialkyl-( m -sulfonated-phenyl)-phosphines and Their Evaluation in Rhodium-Catalyzed Hydrogenation of Maleic Acid in Water. Organometallics. 2009-03-09, 28 (5): 1593–1596 [2021-09-30]. ISSN 0276-7333. doi:10.1021/om800570r （英语）.

[3] Tamara Kovács, Anita Urbanics, Flóra Csatlós, György Keglevich. A study on the deoxygenation of trialkyl-, dialkyl-phenyl- and alkyl-diphenyl phosphine oxides by hydrosilanes. Heteroatom Chemistry. 2017-07, 28 (4): e21376 [2021-09-30]. doi:10.1002/hc.21376 （英语）.

[4] Aagaard, Olav M.; Janssen, Rene A. J.; Buck, Henk M. An ESR study on electron-capture phosphorus-centered radicals in solid matrixes of alkyl/phenylphosphine sulfides and selenides. Recueil des Travaux Chimiques des Pays-Bas, 1989. 108 (7-8): 262-267. ISSN 0165-0513.

[5] Eric A. Standley, Stacey J. Smith, Peter Müller, Timothy F. Jamison. A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes. Organometallics. 2014-04-28, 33 (8): 2012–2018 [2021-09-30]. ISSN 0276-7333. PMC 4006606 . PMID 24803717. doi:10.1021/om500156q （英语）.

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