苯基三甲基硅氧基乙腈
外观
苯基三甲基硅氧基乙腈 | |
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识别 | |
CAS号 | 25438-37-3 ![]() |
性质 | |
化学式 | C11H15NOSi |
摩尔质量 | 205.33 g·mol−1 |
外观 | 无色液体[1] |
密度 | 0.978 g·cm−3[2] |
沸点 | 91 °C(364 K)(0.7 hPa)[1] 100—103 °C(373—376 K)(10 torr)[3] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
苯基三甲基硅氧基乙腈是一种有机化合物,化学式为C11H15NOSi。它可由苯甲醛和三甲基氰硅烷的硅腈化(cyanosilylation)反应制得。[4]它和环己酮在二异丙基氨基锂的存在下于乙二醇二甲醚中反应,可以得到苯基[1-(三甲基硅氧基)环己基]甲酮。[5]它在盐酸中水解,生成扁桃腈。[6]
参考文献
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- ^ "Metal-Organics Catalog" physical property data were obtained from Gelest, Inc. of Morrisville, Pennsylvania (US). Retrieved from SciFinder. [2021-05-26].
- ^ P. Dembech, A. Guerrini, A. Ricci, G. Seconi, M. Taddei. Transformation of α-assisted carbanions into the corresponding trimethylsiloxy derivatives using bis(trimethylsilyl)peroxide. Tetrahedron. 1990-01, 46 (8): 2999–3006 [2021-05-26]. doi:10.1016/S0040-4020(01)88391-5. (原始内容存档于2018-06-16) (英语).
- ^ Maryam Nourian, Farnaz Zadehahmadi, Reihaneh Kardanpour, Shahram Tangestaninejad, Majid Moghadam, Valiollah Mirkhani, Iraj Mohammadpoor-Baltork. Highly efficient oxidative cleavage of alkenes and cyanosilylation of aldehydes catalysed by magnetically recoverable MIL-101. Applied Organometallic Chemistry. 2018-01, 32 (1): e3957 [2021-05-26]. doi:10.1002/aoc.3957 (英语).
- ^ John Wiley & Sons, Inc. (编). Organic Reactions 1. Wiley. 2004-04-15 [2021-05-26]. ISBN 9780471264187. doi:10.1002/0471264180.or031.01. (原始内容存档于2022-03-02) (英语).
- ^ Boyoung Y. Park, Ka Yeon Ryu, Jung Hwan Park, Sang-gi Lee. A dream combination for catalysis: highly reactive and recyclable scandium(iii) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid. Green Chemistry. 2009, 11 (7): 946 [2021-05-26]. ISSN 1463-9262. doi:10.1039/b900254e (英语).
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