环己烷甲酸甲酯
外观
环己烷甲酸甲酯 | |
---|---|
识别 | |
CAS号 | 4630-82-4 |
SMILES |
|
性质 | |
化学式 | C8H14O2 |
摩尔质量 | 142.2 g·mol−1 |
外观 | 液体 |
沸点 | 180 °C[1] |
相关物质 | |
相关化学品 | 3,4-环氧环己烷甲酸甲酯 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
环己烷甲酸甲酯是一种有机化合物,化学式为C8H14O2。它可由环己烷甲酸和甲醇在硫酸存在下回流反应制得。[2]
反应
[编辑]它和正辛醇在三氟甲磺酸五氟苯铵催化下于甲苯中反应,可以得到环己烷甲酸辛酯。[4]
参考文献
[编辑]- ^ Kirillov, N.F., Nikiforova, E.A., Vasyanin, A.N. et al. Synthesis of 16-aryl-15-oxadispiro[5.1.5.3]hexadecane-7,14-diones by reformatsky reaction. Russ J Org Chem 51, 513–517 (2015). doi:10.1134/S1070428015040089
- ^ José Maurício dos Santos Filho, Marcos Venícius Batista de Souza Castro. Synthesis, structural characterization, and antimicrobial activity of novel ferrocene-N-acyl hydrazones designed by means of molecular simplification strategy Celebrating the 100th anniversary of the birth of Professor Paulo Freire. Journal of Organometallic Chemistry. 2022. 979. 122488. doi:10.1016/j.jorganchem.2022.122488
- ^ Malek, Jaroslav. Reductions by metal alkoxyaluminum hydrides. Part II. Carboxylic acids and derivatives, nitrogen compounds, and sulfur compounds. Organic Reactions, 2004. 36. doi:10.1002/0471264180.or036.03.
- ^ Funatomi, Takashi; Wakasugi, Kazunori; Misaki, Tomonori; Tanabe, Yoo. Pentafluorophenylammonium triflate (PFPAT): An efficient, practical, and cost-effective catalyst for esterification, thioesterification, transesterification, and macrolactone formation. Green Chemistry, 2006. 8 (12). 1022-1027. doi:10.1039/b609181b.