9,10-二氫菲
外觀
9,10-二氫菲 | |
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識別 | |
CAS號 | 776-35-2 ![]() |
SMILES |
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性質 | |
化學式 | C14H12 |
摩爾質量 | 180.25 g·mol−1 |
熔點 | 35—35.5 °C(308.1—308.6 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
9,10-二氫菲是一種有機化合物,化學式為C14H12。它可由菲在催化下加氫製得[2]。它可以被混酸[3]或硝酸鉍[4]硝化,得到2,7-二硝基-9,10-二氫菲;它在三氯化鐵催化下和溴反應,可以得到2,7-二溴-9,10-二氫菲[5]。
參考文獻
[編輯]- ^ Hall, D. Muriel; Lesslie, Mary S.; Turner, E. E. 143. 9 : 10-Dihydrophenanthrenes. Part I. The formation of 9 : 10-dihydrophenanthrene from 2 : 2′-disubstituted diphenyls. J. Chem. Soc. (Royal Society of Chemistry (RSC)). 1950, 0 (0): 711–713. ISSN 0368-1769. doi:10.1039/jr9500000711.
- ^ Amer, Ibrahim; Amer, Hamdullah; Ascher, Rachel; Blum, Jochanan; Sasson, Yoel; Vollhardt, K.Peter C. Hydrogenation of arenes by the RhCl3-aliquat® 336 catalyst. Journal of Molecular Catalysis. 1987-02, 39 (2): 185–194. doi:10.1016/0304-5102(87)80062-7.
- ^ Nelsen, Stephen F.; Luo, Yun; Weaver, Michael N.; Lockard, Jenny V.; Zink, Jeffrey I. Optical Spectra of Protected Diamine 10-Bond-Bridged Intervalence Radical Cations Related to N,N,N‘N‘-Tetraalkylbenzidine. The Journal of Organic Chemistry (American Chemical Society (ACS)). 2006-05-01, 71 (11): 4286–4295. ISSN 0022-3263. doi:10.1021/jo060466l.
- ^ Yadav, Ram N.; Salazar, Leonardo; Singh, Amrendra Kumar; Banik, Bimal Krishna. Microwave-induced bismuth nitrate-impregnated clay-mediated novel dinitration of 9,10- dihydrophenanthrene: a precursor for new heterocycles. Heterocyclic Letters, 2018. 8 (2): 273-276.
- ^ Sasaki, Shunsuke; Niko, Yosuke; Klymchenko, Andrey S.; Konishi, Gen-ichi. Design of donor–acceptor geometry for tuning excited-state polarization: fluorescence solvatochromism of push–pull biphenyls with various torsional restrictions on their aryl–aryl bonds. Tetrahedron (Elsevier BV). 2014, 70 (41): 7551–7559. ISSN 0040-4020. doi:10.1016/j.tet.2014.08.002.