1-萘異硫氰酸酯
外觀
1-萘異硫氰酸酯 | |
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IUPAC名 1-Isothiocyanatonaphthalene[1] | |
別名 | 1-Naphthylisothiocyanate; α-Naphthyl isothiocyanate; Kesscocide |
識別 | |
縮寫 | ANIT |
CAS號 | 551-06-4 ![]() |
PubChem | 11080 |
ChemSpider | 10609 |
SMILES |
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InChI |
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InChIKey | JBDOSUUXMYMWQH-UHFFFAOYAA |
Beilstein | 637868 |
UN編號 | 2811 |
EINECS | 208-990-8 |
ChEBI | 35455 |
RTECS | NX9100000 |
MeSH | 1-Naphthylisothiocyanate |
性質 | |
化學式 | C11H7NS |
摩爾質量 | 185.24 g·mol−1 |
外觀 | 白色蠟狀固體[2] |
熔點 | 57—58 °C(330—331 K)[2] |
沸點 | 190 °C(463 K)(20 mmHg)[2] |
危險性 | |
GHS危險性符號![]() ![]() | |
GHS提示詞 | 危險 |
H-術語 | H301, H312, H315, H319, H332, H334, H335 |
P-術語 | P261, P280, P301+310, P305+351+338, P342+311 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1-萘異硫氰酸酯(英語:1-Naphthyl isothiocyanate,縮寫ANIT,或稱為異硫氰酸1-萘酯)是一種有機化合物,分子式C11H17NS,可看作異硫氰酸與1-萘酚形成的酯。
合成
[編輯]它可由1-萘胺和二硫化碳(或硫光氣[3])在三乙胺存在下反應得到[4],也可由α-萘硫脲和氯苯合成[5]。
參考文獻
[編輯]- ^ CID 11080 from PubChem
- ^ 2.0 2.1 2.2 J. D. Kendall, H. G. Suggate. 319. The reactivity of the alkylthio-group in nitrogen ring compounds. Part I. A general method for the preparation of symmetrical and unsymmetrical thiacyanines. Journal of the Chemical Society (Resumed). 1949: 1503 [2023-03-22]. ISSN 0368-1769. doi:10.1039/jr9490001503 (英語).
- ^ Hiroyuki Kai, Yasuhide Morioka, Minoru Tomida, Tadashi Takahashi, Maki Hattori, Kohji Hanasaki, Katsumi Koike, Hiroki Chiba, Shunji Shinohara, Toshiyuki Kanemasa, Yuka Iwamoto, Kohji Takahashi, Yoshitaka Yamaguchi, Takahiko Baba, Takayoshi Yoshikawa, Hideyuki Takenaka. 2-Arylimino-5,6-dihydro-4H-1,3-thiazines as a new class of cannabinoid receptor agonists. Part 2: Orally bioavailable compounds. Bioorganic & Medicinal Chemistry Letters. 2007-07, 17 (14): 3925–3929 [2023-03-22]. doi:10.1016/j.bmcl.2007.04.099. (原始內容存檔於2022-11-22) (英語).
- ^ Raphaël Lebeuf, Isabelle Férézou, Jean Rossier, Stellios Arseniyadis, Janine Cossy. Straightforward Synthesis of the Near-Infrared Fluorescent Voltage-Sensitive Dye RH1691 and Analogues Thereof. Organic Letters. 2009-11-05, 11 (21): 4822–4825 [2023-03-22]. ISSN 1523-7060. doi:10.1021/ol901846g. (原始內容存檔於2023-03-25) (英語).
- ^ a-NAPHTHYL ISOTHIOCYANATE. Organic Syntheses. 1956, 36: 56. doi:10.15227/orgsyn.036.0056.