1-十六醛
外觀
1-十六醛 | |
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IUPAC名 hexadecanal | |
別名 | Hexadecanal; AI3-24252; EINECS 211-111-0; UNII-WQD27655QE |
識別 | |
CAS號 | 629-80-1 ![]() |
PubChem | 984 |
ChemSpider | 959 |
SMILES |
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InChI |
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InChIKey | NIOYUNMRJMEDGI-UHFFFAOYSA-N |
EINECS | 211-111-0 |
ChEBI | 17600 |
KEGG | C00517 |
性質 | |
化學式 | C16H32O |
摩爾質量 | 240.42 g·mol−1 |
熔點 | 34—35 °C(307—308 K)[1] |
沸點 | 160—162 °C(433—435 K)(13 torr)[2] |
溶解性(水) | 難溶 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1-十六醛是一種有機化合物,屬於醛類,化學式為C16H32O。它可由吡啶氯鉻酸鹽氧化1-十六烷醇製得。[3]鎂-氯化亞錫試劑又可將其還原為醇。[4]它和溴乙酸乙酯在鋅、鹽酸存在下反應,可以得到3-羥基十八酸乙酯;[5]3,3-二氟-3-溴丙烯和銦可以與之發生相似反應,生成3,3-二氟十九碳-1-烯-4-醇。[6]
參考文獻
[編輯]- ^ Gordeev, K. Yu.; Serebrennikova, G. A.; Evstigneeva, R. P. Use of anionites in the tetrahydroborate form for obtaining higher liquid aldehydes. Zhurnal Organicheskoi Khimii, 1985. 21 (12): 2615-2616. ISSN 0514-7492
- ^ Enzo Santaniello, Fulvia Milani, Rosangela Casati. Tetrabutylammonium Chlorochromate, A New Mild and Selective Oxidizing Agent. Synthesis. 1983, 1983 (09): 749–751 [2021-11-23]. ISSN 0039-7881. doi:10.1055/s-1983-30500. (原始內容存檔於2018-06-07) (英語).
- ^ Thomas W. Bevan, James Francis-Taylor, Helena Wong, Peter T. Northcote, Joanne E. Harvey. A colourful azulene-based protecting group for carboxylic acids. Tetrahedron. 2018-06, 74 (24): 2942–2955 [2021-11-23]. doi:10.1016/j.tet.2018.04.066 (英語).
- ^ Manobjyoti Bordoloi, Ram P Sharmat, Vaishali Chakraborty. Magnesium-Tin(II) Chloride Dihydrate: A New System for Chemoselective Reduction of Aldehydes into Alcohols in the Presence of Ketones, Ketalization of Ketones and Dehalogenation of Benzyl Halides. Synthetic Communications. 1999-07, 29 (14): 2501–2506 [2021-11-23]. ISSN 0039-7911. doi:10.1080/00397919908086257 (英語).
- ^ Jenny, E. F.; Grob, C. A. The synthesis of erythro-dihydrosphingosine from trans-2-octadecenoic acid. Helvetica Chimica Acta, 1953. 36: 1936-1944. ISSN 0018-019X.
- ^ Hikaru Yanai, Haruna Okada, Azusa Sato, Midori Okada, Takeo Taguchi. Copper-free defluorinative alkylation of allylic difluorides through Lewis acid-mediated C–F bond activation. Tetrahedron Letters. 2011-06, 52 (23): 2997–3000 [2021-11-23]. doi:10.1016/j.tetlet.2011.03.148. (原始內容存檔於2018-06-25) (英語).