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1-十三烷醇

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1-十三烷醇
IUPAC名
Tridecan-1-ol
別名 十三醇
1-十三醇
正十三醇
識別
CAS號 112-70-9  checkY
PubChem 8207
ChemSpider 7915
SMILES
 
  • CCCCCCCCCCCCCO
InChI
 
  • 1/C13H28O/c1-2-3-4-5-6-7-8-9-10-11-12-13/h13H,2-13H2,1H3
InChIKey needed
性質
化學式 C13H28O
摩爾質量 200.36 g·mol−1
外觀 白色固體[1]
密度 0.84 g/cm3[1]
熔點 33 °C(306 K)[2]
沸點 274—280 °C(547—553 K)[1]
溶解性 難溶[1]
危險性
致死量或濃度:
LD50中位劑量
17200 mg/kg (rat, oral)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

1-十三烷醇是一種有機化合物,化學式為C13H28O。它可由十三酸在催化下經氫氣還原製得。[3]三苯基磷咪唑存在下,它和反應,可以得到1-碘十三烷。[4]吡啶氯鉻酸鹽可以將其氧化為1-十三醛[5]它和甲磺醯氯反應,可以得到甲磺酸十三烷基酯。[6]

參考文獻

[編輯]
  1. ^ 1.0 1.1 1.2 1.3 1.4 Record in the GESTIS Substance Database from the IFA英語Institute for Occupational Safety and Health
  2. ^ Dénes Szabó, Ana-Maria Bonto, István Kövesdi, Ágnes Gömöry, József Rábai. Synthesis of novel lipophilic and/or fluorophilic ethers of perfluoro-tert-butyl alcohol, perfluoropinacol and hexafluoroacetone hydrate via a Mitsunobu reaction: Typical cases of ideal product separation. Journal of Fluorine Chemistry. 2005-04, 126 (4): 639–650 [2021-11-29]. doi:10.1016/j.jfluchem.2005.01.017. (原始內容存檔於2018-06-27) (英語). 
  3. ^ Fuchikami, Takamasa; He, De-Hua; Wakasa, Noriko. Process for producing alcohols by catalytic hydrogenation of carboxylic acids. 1995 WO 9524371 A1.
  4. ^ Dimitris Noutsias, Georgios Vassilikogiannakis. First Total Synthesis of Paracaseolide A. Organic Letters. 2012-07-20, 14 (14): 3565–3567 [2021-11-29]. ISSN 1523-7060. doi:10.1021/ol301481t. (原始內容存檔於2021-11-29) (英語). 
  5. ^ Veeresa Gududuru, Kui Zeng, Ryoko Tsukahara, Natalia Makarova, Yuko Fujiwara, Kathryn R. Pigg, Daniel L. Baker, Gabor Tigyi, Duane D. Miller. Identification of Darmstoff analogs as selective agonists and antagonists of lysophosphatidic acid receptors. Bioorganic & Medicinal Chemistry Letters. 2006-01, 16 (2): 451–456 [2021-11-29]. doi:10.1016/j.bmcl.2005.08.096. (原始內容存檔於2020-02-21) (英語). 
  6. ^ Christopher McGuigan, Karen Hinsinger, Laura Farleigh, Ranjith N. Pathirana, Joachim J. Bugert. Novel Antiviral Activity of l -Dideoxy Bicyclic Nucleoside Analogues versus Vaccinia and Measles Viruses in Vitro. Journal of Medicinal Chemistry. 2013-02-14, 56 (3): 1311–1322 [2021-11-29]. ISSN 0022-2623. doi:10.1021/jm301778x. (原始內容存檔於2021-11-29) (英語).