柠檬烯-1,2-环氧化物
| 柠檬烯-1,2-环氧化物 | |
|---|---|
| 别名 | 柠檬烯氧化物 |
| 识别 | |
| CAS号 | 1195-92-2 
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| SMILES |
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| 性质 | |
| 化学式 | C10H16O |
| 摩尔质量 | 152.23 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
柠檬烯-1,2-环氧化物是一种环氧化物，化学式为C10H16O，它存在于一些柑橘属的植物中。[1]
合成及反应
[编辑]柠檬烯-1,2-环氧化物可由柠檬烯和过氧化氢反应制得。[2]它可以被铝汞齐还原为柠檬烯。[3]它可以在柠檬烯-1,2-环氧化物水解酶催化下水解：[4]
参考文献
[编辑]- ^ Kun Zhang, Ying Lin, Zhou-Jian Diao, Wei-Hua Zhang, Sui-Ping Zheng, Shu-Li Liang, Shuang-Yan Han. Enzymatic Process Enhances the Flavour Profile and Increases the Proportion of Esters in Citrus Essential Oils. Chemistry & Biodiversity. 2017. 14 (11): e1700187. doi:10.1002/cbdv.201700187.
- ^ Satoshi Sakaguchi; Yutaka Nishiyama; Yasutaka Ishii. Selective Oxidation of Monoterpenes with Hydrogen Peroxide Catalyzed by Peroxotungstophosphate (PCWP). J. Org. Chem. 1996, 61, 16, 5307–5311. doi:10.1021/jo960275q.
- ^ Peter W. D. Mitchell. Deoxygenation of epoxides with aluminum. Organic Preparations and Procedures International, 1990. 22 (4). doi:10.1080/00304949009356321.
- ^ Armstrong RN, Cassidy CS. New structural and chemical insight into the catalytic mechanism of epoxide hydrolases. Drug Metabolism Reviews. 2000-01-01, 32 (3–4): 327–338. PMID 11139132. S2CID 27172869. doi:10.1081/DMR-100102337.