三乙烯基环三硼氧烷
| 三乙烯基环三硼氧烷 | |
|---|---|
| |
| IUPAC名 2,4,6-tris(ethenyl)-1,3,5,2,4,6-trioxatriborinane | |
| 别名 | Trivinylboroxin, triethenylboroxin, 2,4,6-trivinyl-1,3,5,2,4,6-trioxatriborinane, 2,4,6-trivinylcyclotriboroxane |
| 识别 | |
| CAS号 | 92988-08-4 |
| PubChem | 2734807 |
| ChemSpider | 2016551 |
| SMILES |
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| InChI |
|
| InChIKey | WBRSYBLNSTYNPP-UHFFFAOYSA-N |
| 性质 | |
| 化学式 | C6H9B3O3 |
| 摩尔质量 | 161.57 g·mol−1 |
| 外观 | 无色液体 |
| 密度 | 0.89 g/ml |
| 沸点 | 114 °C（387 K） |
| 危险性 | |
GHS危险性符号
| |
| GHS提示词 | 警告 |
| H-术语 | H302, H315, H319, H335 |
| P-术语 | P261, P264, P264+265, P270, P271, P280, P301+317, P302+352, P304+340, P305+351+338, P319, P321, P330, P332+317 |
| 主要危害 | 可溶 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
应用
[编辑]三乙烯基环三硼氧烷可用于制备苯乙烯衍生物[2]及乙烯酯。[3]
参考文献
[编辑]- ^ Bower, John F.; Williams, Andrew J.; Woodward, Hannah L.; Szeto, Peter; Lawrence, Ron M.; Gallagher, Timothy. Reactivity of cyclic sulfamidates towards phosphonate-stabilised enolates: synthesis and applications of α-phosphono lactams. Organic & Biomolecular Chemistry. 2007, 5 (16): 2636–2644. PMID 18019539. doi:10.1039/B706315F.
- ^ Coleman, Claire M.; O'Shea, Donal F. New Organolithium Addition Methodology to Diversely Functionalized Indoles. Journal of the American Chemical Society. 1 April 2003, 125 (14): 4054–4055. PMID 12670219. doi:10.1021/ja034283h.
- ^ Staderini, Matteo; Gambardella, Alessia; Lilienkampf, Annamaria; Bradley, Mark. A Tetrazine-Labile Vinyl Ether Benzyloxycarbonyl Protecting Group (VeZ): An Orthogonal Tool for Solid-Phase Peptide Chemistry (PDF). Organic Letters. 1 June 2018, 20 (11): 3170–3173. PMID 29791161. doi:10.1021/acs.orglett.8b00898.