氯化[吡啶-2,6-二(2,1-亞苯基)]金
外觀
氯化[吡啶-2,6-二(2,1-亞苯基)]金 | |
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IUPAC名 (SP-4-2)-Chloro[(2,6-pyridinediyl-κN)di(2,1-phenylene-κC)]gold | |
識別 | |
CAS號 | 211680-78-3 ![]() |
SMILES |
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性質 | |
化學式 | C17H11AuClN |
摩爾質量 | 461.7 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
氯化[吡啶-2,6-二(2,1-亞苯基)]金是一種配位化合物,化學式為C17H11AuClN,它可由氯化[2-(6-苯基-2-吡啶基)苯基]汞和氯金酸鉀(KAuCl4)在乙腈中回流反應得到。[1]它和三氟乙酸銀在二氯甲烷中反應,氯可以被三氟乙酸根取代。[1]它在室溫下和1,3,5-三氮雜-7-磷雜金剛烷(PTA)反應,得到[C17H11NAu-PTA]PF6。[2]在相應的反應條件下,也能得到含有新的Au-C鍵的有機金化合物。[3][4]
參考文獻
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- ^ Sophie Jürgens, Valeria Scalcon, Natalia Estrada-Ortiz, Alessandra Folda, Federica Tonolo, Christian Jandl, Duncan L. Browne, Maria Pia Rigobello, Fritz E. Kühn, Angela Casini. Exploring the C^N^C theme: Synthesis and biological properties of tridentate cyclometalated gold(III) complexes. Bioorganic & Medicinal Chemistry. 2017-10, 25 (20): 5452–5460 [2019-10-15]. doi:10.1016/j.bmc.2017.08.001. (原始內容存檔於2019-08-26) (英語).
- ^ Vonika Ka-Man Au, Keith Man-Chung Wong, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Cyclometalated N -Heterocyclic Carbene-Containing Organogold(III) Complexes: Synthesis, Characterization, Electrochemistry, and Photophysical Studies. Journal of the American Chemical Society. 2009-07, 131 (25): 9076–9085 [2019-10-15]. ISSN 0002-7863. doi:10.1021/ja9027692 (英語).
- ^ Vonika Ka-Man Au, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Metallogels of Bis-Cyclometalated Alkynylgold(III) Complexes. Inorganic Chemistry. 2013-01-18, 52 (2): 558–567 [2019-10-15]. ISSN 0020-1669. doi:10.1021/ic3007519. (原始內容存檔於2020-10-30) (英語).