4,4'-偶氮吡啶
| 4,4'-偶氮吡啶 | |
|---|---|
| |
| 識別 | |
| CAS號 | 2632-99-7 
|
| 性質 | |
| 化學式 | C10H8N4 |
| 摩爾質量 | 184.2 g·mol−1 |
| 外觀 | 橙色針狀晶體 |
| 熔點 | 107—108 °C（380—381 K）[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
4,4'-偶氮吡啶是一種有機化合物，化學式為C10H8N4。它可由4-氨基吡啶和10%次氯酸鈉溶液反應製得，[1]或由1,2-二(4-吡啶基)肼和氧氣在DMF中於80 °C反應得到。[2]它和氰化鎳在甲苯中回流反應，可以得到四氰合鎳(II)酸(4,4'-偶氮吡啶)合鎳(II)。[3]它和五羰基氯化錸在四氫呋喃/甲苯中回流反應，可以得到三羰基(4,4'-偶氮吡啶)氯化錸四聚體。[4]
參考文獻
[編輯]- ^ 1.0 1.1 Jean Pierre Launay, Myriam Tourrel-Pagis, Jean Francois Lipskier, Valerie Marvaud, Christian Joachim. Control of intramolecular electron transfer by a chemical reaction. The 4,4'-azopyridine/1,2-bis(4-pyridyl)hydrazine system. Inorganic Chemistry. 1991-03, 30 (5): 1033–1038 [2022-11-07]. ISSN 0020-1669. doi:10.1021/ic00005a029. （原始內容存檔於2022-11-07） （英語）.
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- ^ Shih-Sheng Sun, Alistair J. Lees. Self-Assembly Triangular and Square Rhenium(I) Tricarbonyl Complexes: A Comprehensive Study of Their Preparation, Electrochemistry, Photophysics, Photochemistry, and Host−Guest Properties. Journal of the American Chemical Society. 2000-09-01, 122 (37): 8956–8967 [2022-11-07]. ISSN 0002-7863. doi:10.1021/ja001677p. （原始內容存檔於2022-11-07） （英語）.