二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑

二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑
識別
CAS號	194346-40-2
SMILES	[Cl-][Pt+2]([Cl-])([P]12CN3CN(CN(C3)C1)C2)[P]45CN6CN(CN(C6)C4)C5;
性質
化學式	H24Cl2N6P2Pt
摩爾質量	436.17 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑是一種配位化合物，化學式為PtCl₂P₂C₁₂H₂₄N₆。它可由四氯合鉑(II)酸鉀和1,3,5-三氮雜-7-磷雜金剛烷（PTA）在乙醇中反應製得，^[1]，或通過PtCl2(COD)（COD=1,5-環辛二烯）和PTA反應得到。^[2]它在0.1 mol/L的鹽酸溶液中可以結晶出無色的cis-[PtCl₂(PTAH)₂]Cl₂晶體。^[1]它的配位氯可以被含硫配體取代。^[3]

參考文獻

^ ^1.0 ^1.1 Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.¹ Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. doi:10.1021/ic970238x.
^ Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. doi:10.1016/j.inoche.2004.11.006.
^ Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. doi:10.1021/ic4006746.

[ic-1] 1.0 ^1.1 Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.¹ Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. doi:10.1021/ic970238x.

[2] Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. doi:10.1016/j.inoche.2004.11.006.

[3] Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. doi:10.1021/ic4006746.

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