1,4-二氮雜環八硫
外觀
1,4-二氮雜環八硫 | |
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別名 | 1,4-六硫二亞胺 1,4-二亞氨基六硫 1,2,3,4,6,7-六硫雜-5,8-二氮雜環辛烷 |
識別 | |
CAS號 | 1003-76-5 ![]() |
性質 | |
化學式 | H2N2S6 |
摩爾質量 | 222.42 g·mol−1 |
外觀 | 無色晶體 |
熔點 | 133 °C(406 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1,4-二氮雜環八硫是一種無機化合物,化學式為H2N2S6。它可由氨和二氯化二硫反應製得。[1]它熔化時分解,經四氮化四硫和二氮化四硫分解為硫、氮氣和氨氣。[2]它在四氫呋喃中可以被乙基鋰脫質子,得到S6N2H−和S6N22−。[3]它和乙酸苯汞反應,可以得到不穩定的(C6H5HgN)2S6。[4]
參考文獻
[編輯]- ^ 1.0 1.1 H. G. Heal. Isomers of Hexasulphur Diimide. Nature. 1963-07, 199 (4891): 371–371 [2022-12-07]. ISSN 0028-0836. doi:10.1038/199371a0. (原始內容存檔於2022-12-07) (英語).
- ^ Yoshiyuki Kudo, Teruyoshi Kimura, Shuichi Hamada. The Pyrolysis of 1,2,3,4,6,7-Hexathia-5,8-diazocine. Bulletin of the Chemical Society of Japan. 1990-01, 63 (1): 235–240 [2022-12-07]. ISSN 0009-2673. doi:10.1246/bcsj.63.235 (英語).
- ^ T. Chivers, K. J. Schmidt. Sulphur–nitrogen anions: 14 N and 15 N NMR investigations of the deprotonation of cyclic sulphur imides and sulphur–ammonia solutions. Canadian Journal of Chemistry. 1992-03-01, 70 (3): 710–718 [2022-12-07]. ISSN 0008-4042. doi:10.1139/v92-095 (英語).
- ^ Robert J. Ramsay, Henry G. Heal, Henri Garcia-Fernandez. Mercury and organomercury drivatives of cyclodiazahexathiane and cycloazaheptathiane: preparation and decomposition. Journal of the Chemical Society, Dalton Transactions. 1976, (3): 234 [2022-12-07]. ISSN 0300-9246. doi:10.1039/dt9760000234 (英語).
延伸閱讀
[編輯]- Joe Bojes, Tristram Chivers. Sulphur–nitrogen anions: formation from azide ion and elemental sulphur and their role in the synthesis of cyclic sulphur imides. Journal of the Chemical Society, Dalton Transactions. 1975, (16-17): 1715 [2022-12-07]. ISSN 0300-9246. doi:10.1039/dt9750001715 (英語).