粉红螺旋聚孢霉素B

粉红螺旋聚孢霉素B
识别
CAS号	2974027-82-0
SMILES	O=C1C2=CC=C(O)C(O)=C2CN3C=CC=C13;
性质
化学式	C12H9NO3
摩尔质量	215.2 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

粉红螺旋聚孢霉素B（英语：Clonorosin B）是一种有机化合物，化学式为C₁₂H₉NO₃，它最初于2021年从粉红螺旋聚孢霉（Clonostachys rosea）中分离得到。但该物质的结构最初被错误地定为5-羟基-9H-吡咯并[1,2-a]吲哚-8-甲酸^[1]，后来被更正为6,7-二氢吡咯并[1,2-b]异喹啉-10(5H)-酮。^[2]它可以2,3-二甲氧基溴化苄和吡咯-2-甲酸甲酯为原料合成得到。^[3]

参考文献

^ Chun-Xiao Jiang; et al. Indole Alkaloids from a Soil-Derived Clonostachys rosea. J. Nat. Prod. 2021, 84, 9, 2468–2474. doi:10.1021/acs.jnatprod.1c00457.
^ Chun-Xiao Jiang; et al. Correction to Indole Alkaloids from a Soil-Derived Clonostachys rosea. J. Nat. Prod. 2022, 85, 9, 2252–2253. doi:10.1021/acs.jnatprod.2c00778.
^ Yong-Ying Han; et al. Synthesis of the Corrected Structure Assigned to Clonorosin B, an Alkaloid Obtained from the Soil-derived Fungus Clonostachys rosea YRS-06. J. Nat. Prod. 2024, doi:10.1021/acs.jnatprod.4c00777.

[1] Chun-Xiao Jiang; et al. Indole Alkaloids from a Soil-Derived Clonostachys rosea. J. Nat. Prod. 2021, 84, 9, 2468–2474. doi:10.1021/acs.jnatprod.1c00457.

[2] Chun-Xiao Jiang; et al. Correction to Indole Alkaloids from a Soil-Derived Clonostachys rosea. J. Nat. Prod. 2022, 85, 9, 2252–2253. doi:10.1021/acs.jnatprod.2c00778.

[3] Yong-Ying Han; et al. Synthesis of the Corrected Structure Assigned to Clonorosin B, an Alkaloid Obtained from the Soil-derived Fungus Clonostachys rosea YRS-06. J. Nat. Prod. 2024, doi:10.1021/acs.jnatprod.4c00777.

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