跳转到内容

三羰基氯化甘氨酸钌(II)

维基百科,自由的百科全书
三羰基氯化甘氨酸钌(II)
别名 CORM-3
识别
CAS号 475473-26-8  checkY
PubChem 91886169
ChemSpider 77485395
SMILES
 
  • [C-]#[O+].[C-]#[O+].[C-]#[O+].C(C(=O)O)N.Cl[Ru]
性质
化学式 C5H4ClNO5Ru
摩尔质量 294.61 g·mol−1
外观 黄色固体
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

三羰基氯化甘氨酸钌(II)是一种有机钌化合物,化学式为RuCl(H2NCH2CO2)(CO)3。它可由三羰基二氯化钌二聚体甘氨酸钠反应制得。[1]它可以释放英语Carbon monoxide-releasing molecules一氧化碳分子。[2][3]

参考文献

[编辑]
  1. ^ Clark, James E.; Naughton, Patrick; Shurey, Sandra; Green, Colin J.; Johnson, Tony R.; Mann, Brian E.; Foresti, Roberta; Motterlini, Roberto. Cardioprotective Actions by a Water-Soluble Carbon Monoxide–Releasing Molecule. Circulation Research. 2003, 93 (2): e2–8. PMID 12842916. S2CID 784328. doi:10.1161/01.RES.0000084381.86567.08. 
  2. ^ Santos-Silva, Teresa; Mukhopadhyay, Abhik; Seixas, João D.; Bernardes, Gonçalo J. L.; Romão, Carlos C.; Romão, Maria J. CORM-3 Reactivity toward Proteins: The Crystal Structure of a Ru(II) Dicarbonyl−Lysozyme Complex. Journal of the American Chemical Society. 2011, 133 (5): 1192–1195. PMID 21204537. doi:10.1021/ja108820s. 
  3. ^ Urban, Reinhold; Krämer, Roland; Mihan, Shahram; Polborn, Kurt; Wagner, Barbara; Beck, Wolfgang. Metal complexes of biologically important ligands, LXXXVII α-amino carboxylate complexes of palladium(II), iridium(III) and ruthenium(II) from chloro-bridged ortho-metallated metal compounds and [(OC)3Ru(Cl)(μ-Cl)]2. Journal of Organometallic Chemistry. 1996, 517 (1–2): 191–200. doi:10.1016/0022-328X(96)06166-9.