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9-菲甲醛

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9-菲甲醛
识别
CAS号 4707-71-5  checkY
性质
化学式 C15H10O
摩尔质量 206.24 g·mol−1
外观 浅黄色
熔点 101 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

9-菲甲醛是一种有机化合物,化学式为C15H10O。它可由9-菲甲醇的氧化[2]或9-锂基菲的甲酰化[3]制得。它和苯硼酸在催化下反应,可以得到(αS)-α-苯基-9-菲甲醇。[4]乙酸钯催化下,它环己烷中加热,可以得到一氧化碳[5]

参考文献

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  1. ^ Symmetrical triad prototropic systems. Part IX. The influence of polynuclear aryl groups upon mobility and equilibrium in the αγ-diarylmethyleneazomethine system. J. Chem. Soc., 1933, 37-45. doi:10.1039/JR9330000037.
  2. ^ Bis(2,2'-bipyridyl)copper(II) permanganate (BBCP): A mild and versatile oxidant in organic synthesis. Tetrahedron (1984), 40(23), 5001-5004. doi:10.1016/S0040-4020(01)91340-7.
  3. ^ Bifunctional antitumor agents. Derivatives of pyrrolo[9, 10-b]phenanthrene—A DNA intercalative delivery template. Tetrahedron (1997), 53(43), 14599-14614. doi:10.1016/S0040-4020(97)00991-5.
  4. ^ Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis. ACS Catalysis (2019), 9(2), 1457-1463. doi:10.1021/acscatal.8b04787.
  5. ^ A general and efficient aldehyde decarbonylation reaction by using a palladium catalyst. Chemical Communications (Cambridge, United Kingdom) (2012), 48(35), 4253-4255. doi:10.1039/C2CC31144E.