铁屎米-6-酮
外观
铁屎米-6-酮 | |
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英文名 | Canthin-6-one |
别名 | 6-铁屎米酮 |
识别 | |
CAS号 | 479-43-6 ![]() |
SMILES |
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性质 | |
化学式 | C14H8N2O |
摩尔质量 | 220.23 g·mol−1 |
外观 | 白色晶体[1] |
熔点 | 161~163 °C[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
铁屎米-6-酮(6H-吲哚并[3,2,1-de][1,5]萘啶-6-酮)是一种有机化合物,化学式为C14H8N2O。它可由8-(2-氯苯基)-1,5-萘啶-2-酮和碳酸铯在N,N'-二甲基乙二胺和碘化亚铜的催化下反应制得。[2]它在钯催化下加氢,可以得到4,5-二氢铁屎米-6-酮;它也可以被mCPBA氧化为铁屎米-6-酮-N-氧化物。[1]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Gerardo Cebrián-Torrejón, Nicolas Mackiewicz, Rafael P. Vázquez-Manrique, Alain Fournet, Bruno Figadère, Julien Nicolas, Erwan Poupon. Solution Phase and Nanoparticular Biosynthetically Inspired Interconnections in the Canthin-6-one β-Carboline Series and Study of Phenotypic Properties on C. elegans. European Journal of Organic Chemistry. 2013. 26. 5821-5828. doi:10.1002/ejoc.201300770.
- ^ Gollner, Andreas; Koutentis, Panayiotis A. Two-Step Total Syntheses of Canthin-6-one Alkaloids: New One-Pot Sequential Pd-Catalyzed Suzuki−Miyaura Coupling and Cu-Catalyzed Amidation Reaction. Organic Letters (2010), 12 (6), 1352-1355. doi:10.1021/ol100300s.