硫代樟脑
外观
硫代樟脑 | |
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识别 | |
CAS号 | 7519-74-6 ![]() |
性质 | |
化学式 | C10H16S |
摩尔质量 | 168.3 g·mol−1 |
熔点 | 119 °C(392 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
硫代樟脑是一种有机硫化合物,化学式为C10H16S。它可由樟脑和五硫化二磷[2][3]、劳森试剂[4]等硫化试剂反应得到。在甲基三氧化铼的催化下,它可以被过氧化氢氧化为S-氧化硫代樟脑;[5]过氧化氢/氯化亚砜也可将其转化为樟脑。[6]
参考文献
[编辑]- ^ Schaumann, Ernst; Wriede, Ulrich; Ruehter, Gerd. New access to thiocarbonyl compounds. Angewandte Chemie, 1983. 95 (1): 52-53. ISSN 0044-8249.
- ^ Vivek Polshettiwar, Manisha Nivsarkar, Deepak Paradashani, M.P. Kaushik. Thionation of carbonyl compounds using phosphorus pentasulfide and hexamethyldisiloxane under microwave irradiations. Journal of Chemical Research. 2004-07, 2004 (7): 474–476 [2022-04-10]. ISSN 1747-5198. doi:10.3184/0308234042037149 (英语).
- ^ Vivek Polshettiwar, M.P. Kaushik. A new, efficient and simple method for the thionation of ketones to thioketones using P4S10/Al2O3. Tetrahedron Letters. 2004-08, 45 (33): 6255–6257 [2022-04-10]. doi:10.1016/j.tetlet.2004.06.091. (原始内容存档于2018-06-25) (英语).
- ^ David L. Gamble, William P. Hems, Brian Ridge. Studies on the preparation of camphorylidene derivatives of α-amino acids. Journal of the Chemical Society, Perkin Transactions 1. 2001, (3): 248–260 [2022-04-10]. doi:10.1039/b007659g.
- ^ Ruili Huang, James H. Espenson. A Convenient Preparation of Sulfines (R 2 CSO) from Thioketones. The Journal of Organic Chemistry. 1999-09-01, 64 (18): 6935–6936 [2022-04-10]. ISSN 0022-3263. doi:10.1021/jo990967p (英语).
- ^ Kiumars Bahrami, Mohammad M. Khodaei, Azita Farrokhi. H2O2/SOCl2: a useful reagent system for the conversion of thiocarbonyls to carbonyl compounds. Tetrahedron. 2009-09, 65 (36): 7658–7661 [2022-04-10]. doi:10.1016/j.tet.2009.06.110. (原始内容存档于2018-06-29) (英语).