四氯合铁(III)酸四乙基铵是一种配位化合物,化学式为(N(C2H5)4)FeCl4,或简写为(Et4N)FeCl4。它可由四乙基氯化铵和三氯化铁在乙醇中反应得到,它在四氢呋喃中可以结晶。[3](Et4N)2[Fe2S2Cl4]和氯化氢反应,也能得到该化合物。[1]它和硝酸银在dppa存在下反应,可以得到[Ag3(μ-Cl)(μ3-Cl)(μ-dppa)3][FeCl4]。[4]
- ^ 1.0 1.1 Camly T. Tran, Eunsuk Kim. Acid-Dependent Degradation of a [2Fe–2S] Cluster by Nitric Oxide. Inorganic Chemistry. 2012-10-01, 51 (19): 10086–10088 [2022-11-12]. ISSN 0020-1669. doi:10.1021/ic301676f. (原始内容存档于2022-11-12) (英语).
- ^ 2.0 2.1 D. Wyrzykowski, Agnieszka Pattek-Janczyk, T. Maniecki, Katarzyna Zaremba, Z. Warnke. Thermal properties of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III). Journal of Thermal Analysis and Calorimetry. 2008-01, 91 (1): 279–284 [2022-11-12]. ISSN 1388-6150. doi:10.1007/s10973-006-8269-8 (英语).
- ^ Martin Lutz, Yuxing Huang, Marc-Etienne Moret, Robertus J. M. Klein Gebbink. Phase transitions and twinned low-temperature structures of tetraethylammonium tetrachloridoferrate(III). Acta Crystallographica Section C Structural Chemistry. 2014-05-01, 70 (5): 470–476 [2022-11-12]. ISSN 2053-2296. doi:10.1107/S2053229614007955. (原始内容存档于2022-11-12).
- ^ Hua-Tian Shi, Taike Duan, Chao Xu, Qian-Feng Zhang. Syntheses and Structures of Trinuclear Trigonal-bipyramidal Silver(I) Complexes with Bis(diphenylphosphino)amide Ligands. Zeitschrift für Naturforschung B. 2009-02-01, 64 (2): 204–208 [2022-11-12]. ISSN 1865-7117. doi:10.1515/znb-2009-0210. (原始内容存档于2022-11-12) (英语).
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| 铁(-II) | |
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| 铁(0) | |
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| 铁(I) |
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| 铁(0,II) | |
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| 铁(II) |
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| 铁(0,III) | |
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| 铁(II,III) | |
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| 铁(III) |
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| 铁(VI) | |
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