四氯化二羰基二铂

四氯化二羰基二铂
识别
CAS号	17522-99-5
PubChem	130476784
SMILES	C(#[O])[Pt+2]1([Cl-])[Cl-][Pt+2](C#[O])([Cl-])[Cl-]1;
InChIKey	ITTDXEJZAMBOHT-UHFFFAOYSA-J
EINECS	241-519-4
性质
化学式	C2Cl4O2Pt2
摩尔质量	588 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四氯化二羰基二铂是第一个被分离出来的金属羰基配合物，化学式为[Pt(CO)Cl₂]₂，它最初由保罗·许岑贝格尔（英语：Paul Schützenberger）于1868年合成出来。^[1]它溶解在氯化亚砜中，并暴露于一氧化碳气氛中，可以得到Pt(CO)
2Cl
2。^[2]烯烃也能与之反应，得到相应的cis-PtCl
2(CO)(烯烃)配合物。^[3]

参考文献[编辑]

^ Elschenbroich, Christoph. Organometallics. 3rd. Weinheim: Wiley-VCH. 2006. ISBN 3-527-29390-6. OCLC 64305455.
^ Belli Dell'Amico, Daniela; Calderazzo, Fausto; Veracini, Carlo Alberto; Zandona, Nicola (1984). "Comparison between carbonyl derivatives of palladium and those of nickel and platinum". Inorganic Chemistry. 23 (19): 3030–3033. doi:10.1021/ic00187a027. ISSN 0020-1669.
^ Alper, Howard; Huang, Yujin; Belli Dell'Amico, Daniela; Calderazzo, Fausto; Pasqualetti, Nicola; Veracini, Carlo Alberto. Synthesis of carbonyl-olefin complexes of platinum(II), PtX2(CO)(olefin), and the catalytic hydrochlorination of olefins. Organometallics. 1991, 10 (6): 1665–1671. ISSN 0276-7333. doi:10.1021/om00052a010 （英语）.

[:0-1] Elschenbroich, Christoph. Organometallics. 3rd. Weinheim: Wiley-VCH. 2006. ISBN 3-527-29390-6. OCLC 64305455.

[:2-2] Belli Dell'Amico, Daniela; Calderazzo, Fausto; Veracini, Carlo Alberto; Zandona, Nicola (1984). "Comparison between carbonyl derivatives of palladium and those of nickel and platinum". Inorganic Chemistry. 23 (19): 3030–3033. doi:10.1021/ic00187a027. ISSN 0020-1669.

[:6-3] Alper, Howard; Huang, Yujin; Belli Dell'Amico, Daniela; Calderazzo, Fausto; Pasqualetti, Nicola; Veracini, Carlo Alberto. Synthesis of carbonyl-olefin complexes of platinum(II), PtX2(CO)(olefin), and the catalytic hydrochlorination of olefins. Organometallics. 1991, 10 (6): 1665–1671. ISSN 0276-7333. doi:10.1021/om00052a010 （英语）.

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