亚苄基丙二腈
外观
亚苄基丙二腈 | |
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英文名 | 2-(Phenylmethylene)propanedinitrile |
别名 | 1,1-二氰基-2-苯基乙烯 |
识别 | |
CAS号 | 2700-22-3 ![]() |
SMILES |
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性质 | |
化学式 | C10H6N2 |
摩尔质量 | 154.17 g·mol−1 |
外观 | 无色晶体[1] |
熔点 | 83 °C(356 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
亚苄基丙二腈是一种有机化合物,化学式为C10H6N2。它可由苯甲醛和丙二腈反应得到。[2]它和硝基甲烷反应,得到2-(2-硝基-1-苯乙基)丙二腈。[3]和2-碘-2-甲基丙烷在过氧化苯甲酰和三乙基铝的存在下反应,得到α-叔丁基苄基丙二腈。[4]
参考文献
[编辑]- ^ 1.0 1.1 G. Rajesh Krishnan, Krishnapillai Sreekumar. First Example of Organocatalysis by Polystyrene-Supported PAMAM Dendrimers: Highly Efficient and Reusable Catalyst for Knoevenagel Condensations. European Journal of Organic Chemistry. 2008-10, 2008 (28): 4763–4768 [2020-07-04]. doi:10.1002/ejoc.200800516 (英语).
- ^ Samahe Sadjadi, Maryam Akbari, Fatemeh Ghoreyshi Kahangi, Majid M. Heravi. Acidic polymer containing sulfunic acid and carboxylic acid groups heterogenized with natural clay: A novel metal free and heterogeneous catalyst for acid-catalyzed reactions. Polyhedron. 2020-03, 179: 114375 [2020-07-04]. doi:10.1016/j.poly.2020.114375 (英语).
- ^ David Michaud, Françoise Texier-Boullet, Jack Hamelin. Michael Monoaddition of Nitromethane on Gem-Diactivated Alkenes in Dry Media Coupled with Microwave Irradiation. Tetrahedron Letters. 1997-10, 38 (43): 7563–7564 [2020-07-04]. doi:10.1016/S0040-4039(97)10035-1. (原始内容存档于2022-04-26) (英语).
- ^ Jing-Yuan Liu, Yoeng-Jiunn Jang, Wen-Wei Lin, Ju-Tsung Liu, Ching-Fa Yao. Triethylaluminum- or Triethylborane-Induced Free Radical Reaction of Alkyl Iodides and α,β-Unsaturated Compounds. The Journal of Organic Chemistry. 2003-05, 68 (10): 4030–4038 [2020-07-04]. ISSN 0022-3263. doi:10.1021/jo020681b (英语).