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二甲硅烷基甲烷

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二甲硅烷基甲烷
识别
CAS号 1759-88-2  checkY
性质
化学式 CH8Si2
摩尔质量 76.25 g·mol−1
密度 0.6929 g·cm−3(4 °C)[1]
沸点 15 °C(288 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二甲硅烷基甲烷1,3-二硅杂丙烷)是一种有机硅化合物,化学式为CH8Si2,它是甲基乙硅烷的同分异构体。它可由二(三氯硅烷基)甲烷(或二(溴硅烷基)甲烷[3])和氢化铝锂反应得到。[4]它在催化下和反应,可以得到三[(甲硅烷基甲基)甲硅烷基]胺等多种产物。[5]

参考文献

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  1. ^ Batuev, M. I.; Ponomarenko, V. A.; Matveeva, A. D.; Petrov, A. D. Physical and chemical properties of silicohydrocarbons (disilylmethane, 1,2-disilylethane, dipropylsilane, and hexylsilane). Doklady Akademii Nauk SSSR, 1954. 95: 805-808. ISSN 0002-3264.
  2. ^ Joachim Zech, Hubert Schmidbaur. Synthetic pathways to disilylmethane, H 3 SiCH 2 SiH 3 , and methyldisilane, CH 3 SiH 2 SiH 3. Chemische Berichte. 1990-11, 123 (11): 2087–2091 [2022-05-29]. ISSN 0009-2940. doi:10.1002/cber.19901231102 (英语). 
  3. ^ Rudolf Hager, Oliver Steigelmann, Gerhard Müller, Hubert Schmidbaur. A synthetic route to poly(silyl)methanes via poly(phenylsilyl)methanes and poly(bromosily)methanes. Chemische Berichte. 1989-11, 122 (11): 2115–2119 [2022-05-29]. ISSN 0009-2940. doi:10.1002/cber.19891221111 (英语). 
  4. ^ Khandelwal, Manish; Kerrigan, Sean; Girard, Jean-Marc; Sanchez, Antonio; Zhang, Peng. Si-containing film forming composition and method of forming Si-containing film on substrate. 2017 WO 2017165626 A1.
  5. ^ Kerrigan, Sean; Sanchez, Antonio. Catalytic dehydrogenative coupling of carbosilanes with ammonia, amines and amidines. 2016 WO 2016160991 A1.