α,α,α-三硝基甲苯
外观
α,α,α-三硝基甲苯 | |
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英文名 | (Trinitromethyl)benzene α,α,α-Trinitrotoluene |
别名 | (三硝基甲基)苯 |
识别 | |
CAS号 | 67483-29-8 ![]() |
SMILES |
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性质 | |
化学式 | C7H5N3O6 |
摩尔质量 | 227.13 g·mol−1 |
熔点 | 4.5 °C(277.6 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
α,α,α-三硝基甲苯是一种有机化合物,化学式为C7H5N3O6,是三硝基甲苯的同分异构体之一。它可由α,α-二硝基苄基钾和四氧化二氮在三氯甲烷中反应得到。[2]它可以用于制备α-C-硝基腙。[3]
参考文献
[编辑]- ^ Titov, A. I.; Smirnov, V. V. Effect of complex formation, ionization, and isomerization of organic compounds on their chemical activity in nitration. Synthesis of phenyltrinitromethane and its properties. Doklady Akademii Nauk SSSR, 1952. 83. 243-246. ISSN: 0002-3264.
- ^ Makhova, N. N.; Ovchinnikov, I. V.; Dubonos, V. G.; Strelenko, Yu. A.; Khmel?nitski, L. I. New methods for preparation of nitrile oxides and the corresponding disubstituted furoxans by reaction of N2O4 with salts of substituted dinitromethanes. Izvestiya Akademii Nauk, Seriya Khimicheskaya, 1993. 1: 147-151.
- ^ Shvarts, I. Sh.; Krayushkin, M. M.; Sevost'yanova, V. V.; Yarovenko, V. N. Synthesis and properties of α-C-nitrohydrazones. 2. Reaction of hydrazines with trinitromethyl components(俄文). Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya. 1979. 5. 1069-1073.